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Beilstein J. Org. Chem. 2014, 10, 449–458, doi:10.3762/bjoc.10.42
Graphical Abstract
Scheme 1: Cycloisomerization/fluorination of functionalized indoles.
Scheme 2: Synthesis of hemiaminal derivatives.
Scheme 3: Reaction on n-hexyl-substituted derivative 1i.
Scheme 4: Mechanism rationale for the formation of 7.